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Preheat the oven to 375 F. Add 1 tablespoon of butter to the cast iron skillet and place it in the oven.
In a large bowl, whisk together the eggs, heavy cream, and salt until fluffy. Add shredded Cheddar cheese and stir to combine.
Using an oven mitt, remove the cast iron skillet from the oven and roll it carefully from side to side to evenly butter the dish with melted butter.
Add chopped broccoli and chopped ham to a buttered cast iron skillet.
Pour the egg and cheddar cheese mixture over the broccoli and ham.
Top evenly with shredded pepper jack cheese.
Bake for 20 minutes until the frittata is no longer wobbly in the center.
Transfer the frittata to a wire rack, and let it rest for 15 minutes before serving.