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Start by preheating your oven to 350F
In a large bowl combine your melted butter, sugar and brown sugar. Mix and add in your eggs. Mix well then add in your buttermilk and vanilla.
Once your wet ingredients are combined set them to the side.
In a separate bowl mix your flour, cocoa powder, baking soda, baking powder and salt. Add to your wet ingredients and fold to combine. Add your hot coffee and Mix together.
Fold until smooth then using a cooked scoop, scoop the batter into a lined muffin tin.
Bake on 350F for 22-24 minutes or until a toothpick comes out smooth.
Allow them to cool completely then ice with chocolate frosting.