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Preheat the oven to 400 degrees F (200 degrees C).
Combine beans, marinara sauce, and Parmesan cheese in a 10-inch ovenproof skillet; stir until evenly coated.
Top with mozzarella cheese and arrange pepperoni slices evenly over the surface. Cover tightly with aluminum foil.
Bake in the preheated oven until heated through, 25 to 30 minutes.
Move oven rack to the upper third of the oven and preheat the broiler.
Remove foil and broil 4 to 5 inches from the heat until the cheese is melted and bubbly, 3 to 4 minutes.
Serve hot with garlic bread or baguette slices.