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Adjust oven rack to lower-middle position and heat broiler.
Pulse bread and chilled butter in food processor until coarsely ground, 7 to 10 pulses; set aside.
Bring 4 quarts water to boil in Dutch oven. Add macaroni and 1 tablespoon salt and cook, stirring often, until tender. Drain macaroni and set aside in colander.
Melt remaining 5 tablespoons butter in now-empty pot over medium-high heat. Whisk in flour, mustard, cayenne, and 1 teaspoon salt and cook for 1 minute.
Slowly whisk in milk until smooth. Bring mixture to boil, reduce heat to medium, and cook, whisking occasionally, until thickened to consistency of heavy cream, about 5 minutes.
Off heat, whisk in cheeses until fully melted. Add macaroni and cook over medium-low heat, stirring constantly, until steaming and heated through, about 6 minutes.
Pour mixture into 13 by 9-inch broiler-safe baking dish. Top with bread-crumb mixture and broil until crumbs are deep golden brown, 3 to 5 minutes, rotating dish if necessary for even browning.
Let rest for 5 minutes. Serve.