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Preheat the oven to 400°F.
Steam the broccoli: In a medium microwave-safe bowl, combine the broccoli and water. Cover with plastic wrap or a lid and microwave until bright green and crisp-tender, about 3 minutes. Drain any excess water.
Make the casserole base: Meanwhile, in a large bowl, whisk together the soup, sour cream, milk, mustard, garlic powder, and salt. Fold in the chicken, rice, steamed broccoli, and 1 cup of the cheese until evenly combined.
Make the topping: In a medium bowl, combine the crushed crackers, melted butter, and remaining 1 cup of cheese and toss to coat.
Assemble and bake: Grease a 9x13-inch baking dish with extra butter. Transfer the broccoli mixture to the greased baking dish and spread it into an even layer. Sprinkle the casserole evenly with the cracker topping. Bake until the crackers are golden and the sides of the casserole are bubbly, about 20 minutes. Let cool slightly and serve. Love the recipe? Leave us stars and a comment below!