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Preheat oven to 425 degrees
Line 2 muffin tins with paper liners, spacing muffins out if possible
In a medium bowl, whisk together flour, cocoa powder, baking soda, baking powder, and salt
In a separate bowl, mix together cooled espresso, vanilla, sugar, eggs and buttermilk
Stream the cooled butter in and whisk to combine
Add the dry ingredients, stirring with a wooden spoon or spatula until barely combined and a few streaks of flour remain
Do not overmix
Gently stir in the chocolate chips, setting aside 3-4 TBSP of chocolate chips for the tops of muffins if desired
Using an ice cream scoop, divide the batter evenly amongst the muffin cups, filling each to the top
Bake for 5 minutes at 425 degrees. Then reduce the temperature to 350 degrees and bake for an additional 10-12 minutes, checking that a toothpick comes out clean before removing from oven
For best results, bake 6 muffins per 12 cup muffin pan, leaving space between muffins
When done baking, immediately place a few of the remaining chocolate chips on top of each muffin. They will melt as the muffins cool
Cool for 5-10 minutes in a draft free area and then remove muffins from pan to cool completely on a wire rack
Dust with confectioner’s sugar before serving