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Preheat your oven to 400 degrees Fahrenheit and line a baking sheet with foil.
Drizzle ½ tablespoon of olive oil over the foil.
Place the broccoli and cauliflower florets on the baking sheet, then position the chicken breasts in the center.
Drizzle the chicken and vegetables with an additional 1 ½ tablespoons of olive oil.
Sprinkle the chicken with ½ to ¾ teaspoon of Cajun seasoning, and season the vegetables with salt and pepper.
Zest the entire lemon over the chicken and vegetables, then squeeze the juice from one lemon on top.
Bake in the oven for 30 minutes or until the chicken reaches an internal temperature of 165 degrees.
After baking, squeeze the juice of the second lemon over the chicken and vegetables before serving.