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Combine all the pork rub ingredients in a bowl and mix to combine.
Using your hands, coat the pork loin with the rub mixture.
Add tomato sauce and reserved syrup to the slow cooker and stir to combine.
Add the pork loin to the slow cooker. Add the peaches, and top the pork with peaches.
Cook on low for 5-6 hours.
You can also cook the pork on low for 8 hours if you want to shred it and make peach-pulled pork. Shred it and mix it with the sauce.
Carve the pork into slices (or shred it and mix it with the sauce), and serve with the slow-cooked peaches.