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Preheat oven to 350°F.
Place the butter in an 8-inch baking dish and melt in the oven.
When the butter has melted, remove from the oven and scatter pecans across the pan.
In a medium mixing bowl, combine the flour, sugar, baking powder, milk, and vanilla. Stir to combine.
Pour the batter over the pecans, do not stir.
Sprinkle brown sugar evenly over the batter, do not stir.
Carefully pour the boiling water over the mixture; do not stir.
Bake for 32-36 minutes, until golden brown.
Cool at least 15 minutes before serving.
Serve warm with vanilla ice cream, if desired.