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Heat a large skillet over MED HIGH/HIGH heat. Add a drizzle of vegetable oil, and once hot, add buns, cut side down. Cook for 30 seconds to a minute (this time will vary), or until golden brown on the bottoms.
Remove to a wire cooling rack, cut sides up.
Heat oil in large skillet over MED-HIGH heat. Add turkey, onion and bell pepper and cook, breaking apart into crumbles as it cooks, about 5 minutes, or until turkey is cooked through and vegetables are beginning to soften. Transfer to colander to drain.
Add chili powder, garlic powder, salt, pepper, mustard, ketchup, barbecue sauce, tomato paste, sugar, vinegar, Worcestershire sauce and water and stir well to combine.
Reduce heat to MED/MED LOW and cook for 10-15 minutes, until mixture has thickened to your liking, stirring often. Remove from heat and serve over toasted buns.