Whisk the flour, cocoa powder, sugar, baking powder, cinnamon, and salt together in a large bowl.
Grate the frozen butter using a box grater. Add it to the flour mixture and combine with a pastry cutter, two forks, or your fingers until the mixture comes together in pea-sized crumbs.
Place in the refrigerator or freezer while you mix the wet ingredients.
Whisk the heavy cream, egg, and vanilla extract together in a small bowl.
Drizzle over the flour mixture, add the 6 ounces of chopped chocolate, and then mix until everything appears moistened.
Pour the dough onto the counter and, with floured hands, work it into a ball as best you can.
Press the dough into an 8-inch disc and, with a sharp knife or bench scraper, cut into 8 wedges.
Place scones on a plate or lined baking sheet and refrigerate for at least 15 minutes and up to 1 day.
Preheat the oven to 425°F (218°C).
Line a large baking sheet with parchment paper or a silicone baking mat.
After refrigerating, arrange the scones 2-3 inches apart on the prepared baking sheet(s).
Bake for 5 minutes. Without removing the scones from the oven, reduce the oven temperature to 400°F (204°C) and continue baking for 16–17 minutes, or until the edges and tops are set.
Remove from the oven and cool for a few minutes while you prepare the glaze.
Whisk the confectioners’ sugar, vanilla, and water together.
Dip the warm scones into the glaze and place on a wire rack with a baking sheet or paper towels underneath to catch the glaze as it drips down.
Before serving, melt the remaining 4 ounces of semi-sweet chocolate in the microwave in 15 second increments, stirring after each increment until melted. Drizzle over the scones.
