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Preheat oven to 350°F. Line two 8-inch round cake pans with parchment paper and spray with baking spray.
In a large bowl, whisk together flour, cocoa powder, sugar, baking powder, baking soda, and salt.
Stir in vegetable oil until dry ingredients are well coated, followed by eggs and vanilla.
Stir in buttermilk until combined, then carefully pour in hot coffee and stir until smooth.
Add batter evenly to prepared cake pans and bake in preheated oven for 30-35 minutes, or until a toothpick entered into the center of the cakes comes out smooth or with moist crumbs.
Cool cake layers slightly in cake pans, then transfer to a wire rack to cool completely before adding Chocolate Fudge Frosting.
Prepare frosting as detailed in Chocolate Fudge Frosting post.
Spread frosting over cooled cake layers.