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Preheat your oven to 250°F (120°C) and prepare a large baking sheet by spraying it with nonstick cooking spray.
In a large bowl, combine the popped popcorn with baking soda, salt, cinnamon, and chipotle pepper if using.
In a saucepan over medium heat, melt the butter, then stir in the brown sugar and honey.
Bring the mixture to a boil, stirring constantly, and let it boil for about 4-5 minutes without stirring.
Remove the saucepan from heat and pour the caramel mixture over the popcorn, tossing to coat evenly.
Spread the coated popcorn onto the prepared baking sheet in an even layer.
Bake in the preheated oven for about 30 minutes, stirring every 10 minutes to ensure even coating.
Once done, remove from the oven and let it cool completely before breaking into pieces.