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In a small bowl, combine brown sugar, chili powder, dried oregano, Cajun seasoning, paprika, and garlic powder. Mix well.
Pat the pork chops dry with a paper towel. Season both sides with salt and pepper, then rub the spice mixture evenly over each chop.
Heat the olive oil in a large skillet over medium-high heat until hot.
Place the pork chops in the skillet and cook for 4-5 minutes on each side, or until they reach an internal temperature of 145°F (63°C) and have a nice caramelized crust.
Remove the pork chops from the skillet and let them rest for 5 minutes before serving.