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Combine flour, sugar, baking powder, rosemary, and salt in a bowl.
Rub diced butter into flour mixture with your hands until pea-sized specks. Do the same with the goat cheese.
Stir in buttermilk and milk all at once, mixing enough just until a dough comes together; do not overmix.
Preheat the oven to 400 degrees F (205 degrees C). Line a baking sheet with parchment paper.
Meanwhile, turn dough out onto a lightly floured work surface; roll out until about 1-inch thick. Make a 4-fold by turning the 2 outside edges together into the center, then fold the entire piece of dough up like a book. Roll out again until 1-inch thick. Make a 3-fold (folding like a trifold wallet).
Roll out dough until about 1-inch thick. Cut biscuits, using a 3-inch cutter.
Transfer biscuits to the prepared baking sheet. Brush biscuits with a bit of buttermilk; sprinkle tops with salt.
Bake in the preheated oven until puffed and golden brown, about 18 minutes. Depending on your oven, you may need to rotate the baking sheet once for even browning.