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Add all the ingredients except the broccoli to the slow cooker. Stir to mix well.
Cook HIGH 2-3 hours or LOW 4-6.
Add broccoli and cook an additional 30 minutes.
Turn on the pressure cooker and select sauté. When hot, add the oil, onion, and bell pepper & cook 3-5 minutes or until veggies are soft. Add garlic and cook an additional minute. Turn off the pressure cooker.
Add chicken, coconut aminos, water, rice vinegar, bell peppers, onion, carrots, ginger, salt, and pepper to the slow cooker. Stir to mix well.
Close lid and seal valve. Set high pressure and cook for 5 minutes. Quick release pressure.
Turn on the IP and select sauté. Mix together arrowroot starch flour & water. Stir mixture into the Instant Pot along with the broccoli. Cook 5-10 minutes or until broccoli is tender and sauce has thickened to your liking.