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Preheat the oven to 400 degrees F (200 degrees C.)
Toss shredded cheese and flour together in a medium bowl. Sprinkle mixture onto frozen pie crust. Add diced ham on top of cheese.
Combine eggs, milk, salt, and dry mustard in a medium bowl. Beat until smooth and pour over cheese and ham.
Place foil around the edges of the crust to protect it from burning.
Bake in the preheated oven until the filling is set and the crust is golden brown, about 1 hour. A knife inserted into the center of the quiche should come out clean.
Garnish with parsley and pimento peppers before serving.