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Preheat the oven to 350 degrees F (175 degrees C). Lightly grease a 9x13-inch baking dish.
Bring water to a boil in a small saucepan. Dissolve 1 cup sugar in boiling water, then add 3 tablespoons butter. Remove from heat; set syrup aside to cool.
Whisk flour, baking powder, and salt together in a large bowl. Cut in ½ cup butter. Stir in milk; mix lightly.
Roll out dough on a floured surface into a rectangle shape about 12 inches long.
Combine rhubarb, cinnamon, and remaining 1 cup sugar in another bowl; spread evenly over dough, leaving a ½-inch border. Roll dough tightly lengthwise; seal the seam. Cut into twelve 1-inch pieces. Arrange rolls in the prepared baking dish. Pour syrup over rolls.
Bake in the preheated oven until lightly browned, about 40 minutes.