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Preheat oven to 350 degrees.
Spray a cupcake pan with non-stick spray.
Place a biscuit into each cupcake. Use your fingers to make a well in each biscuit (The kids loved doing this).
Spoon 1 tablespoon of sauce into each cupcake.
Sprinkle the pepperonis and top with the mozzarella cheese (don't go overboard on the cheese, these are going to rise quite a bit. I learned the hard way)
Bake in the preheated oven for 10-12 minutes until nice and golden brown.
Allow the cupcakes to cool about 5 minutes (they will "deflate" some) before serving.