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Preheat oven to 350°F. Lightly spray a standard muffin pan with nonstick spray and set aside. Gently melt ⅓ cup butter for the muffins and set aside.
In a large bowl, whisk the flour, sugar, baking powder, baking soda, cinnamon, nutmeg, and salt.
In a small bowl, whisk the egg, vanilla, milk, and melted butter.
Stir wet ingredients into dry ingredients, just until evenly combined. Then divide batter evenly between the 12 muffin cup wells.
Bake for 15-20 minutes, or just until the muffin tops spring back lightly to the touch and a toothpick comes out just clean.
Remove pan from oven and let rest for 5 minutes before removing muffins to a cooling rack. If the muffins stick at all, run a sharp thin knife around the perimeter of each muffin to release them from the pan. Let muffins cool completely.
In a small bowl, whisk the sugar and cinnamon. In another small bowl, gently melt the 10 tablespoons of butter.
Quickly roll a muffin in the melted butter, then immediately roll it in the cinnamon sugar, to evenly coat. Repeat with remaining muffins.